We broker crude, technical and refined glycerine between biodiesel producers and the refiners, oleochemical plants and biogas operators who take it. On what decides the price: five numbers, and an offer without them is an enquiry rather than an offer. Glycerol content, water, ash, MONG and residual methanol. On the paperwork, crude glycerine sits in Annex IX Part A, which a surprising number of producers still treat as a disposal problem.
- 1Transesterification at the plant
- 2Crude glycerine drawn off
- 3Methanol stripped, salt and MONG measured
- 4Refined to technical or pharmaceutical grade
- 5Chemical outlet, or energy if it does not pay
Crude glycerine trades on what it still contains: MONG, ash, methanol and water. Refining only pays when the spread to technical grade covers it, otherwise the barrel goes to combustion or digestion.
Two products, several markets
The gap between crude and refined is refining capacity, and it is not evenly distributed. A producer sitting near a refiner has options a producer in the wrong location does not, which is often worth more than a point of purity.
- Crude glycerine, typically around 80 % glycerol, straight from transesterification. Carries salts, methanol and organic residue. Outlets: advanced biofuel and biogas routes, glycerine refiners, and industrial use.
- Technical and refined glycerine, typically 99 % and above, after refining and distillation. Outlets: chemicals, resins, antifreeze, personal care, tobacco humectants and animal feed.
- USP and pharmaceutical grade, the highest specification, with its own documentation requirements and a much narrower buyer list.
Crude, technical and refined, and the gap between them
Glycerine is sold in three broad conditions and they are barely the same trade. Crude glycerine comes off a biodiesel plant as a co-product and is priced as a problem to be solved; refined glycerine is a pharmacopoeia-grade chemical. The distance between them is a refinery, and it shows in the price.
| Parameter | Crude (biodiesel co-product) | Refined USP / EP |
|---|---|---|
| Glycerol content | 80 % min is the common basis; 85 and 88 % also trade | 99.5 % min |
| Water | Roughly 10 to 15 % | Per pharmacopoeia |
| Ash | 2 to 8 % | Effectively nil |
| Salt (NaCl or K salts) | Up to about 4 % | Effectively nil |
| Methanol | Below 0.5 % in well-stripped material | Nil |
| MONG (matter organic non-glycerol) | The line that decides the discount | Not applicable |
| pH | Stated on the offer; alkaline unless neutralised | Per pharmacopoeia |
| Colour | Dark, variable | Water white |
MONG is the number that gets argued about. It is everything organic that is not glycerol: soaps, residual esters, free fatty acid carry-over. A refiner prices high-MONG material down hard because it is what fouls the process, so a seller quoting only glycerol content is quoting half the specification.
Methanol matters for a different reason. Above roughly half a percent it turns a routine bulk liquid into a classification and transport question, and that is a conversation to have before the truck is booked rather than at the gate. The same applies to whether the material is palm, rapeseed, soy or mixed origin, because the certification route follows the feedstock.
What buyers screen on, and how each number is measured
| Parameter | How it is measured | Why the buyer asks |
|---|---|---|
| Glycerol content (purity) | Stated on the certificate of analysis per batch, within the ISO 1614 sampling discipline. | The headline number: roughly 80 % for crude, 99 %+ for refined grades. |
| MONG | Calculated, not measured directly: 100 minus glycerol, minus water, minus ash, per ISO 2464. | The organic impurity load, and the key indicator of refining difficulty. |
| Water | Karl Fischer, the ISO 2097 application. | Roughly 10 to 15 % in crude. Freight and yield: at 80 % purity a tonne contains 800 kg of glycerol. |
| Ash / salt content | Gravimetric, the ISO 2098 method. | Sodium or potassium salts from the catalyst. 2 to 8 % in crude; drives refining cost and rules out some outlets. |
| Methanol | Stated by the supplier per batch; headspace analysis in modern practice. | Residual from transesterification. A safety, transport and classification issue as much as a quality one. |
| pH | The alkalinity or acidity determination of ISO 1614. | Handling, storage and materials compatibility. |
| Colour | APHA or Gardner scale. | Matters most for refined and technical grades. |
| Chlorides and sulphates | Per the certificate of analysis. | Corrosion and downstream process impact. |
| Feedstock origin | Documentation, not the laboratory. | Vegetable, animal or used cooking oil origin decides the certification route and, for some outlets, acceptability. |
| Certification | The ISCC EU chain, where claimed. | Compliance value where the glycerine heads into the biofuel or biogas chain. |
| Heavy metals, DEG/MEG | Per the certificate of analysis. | For refined, food and pharmaceutical grades. |
The arithmetic of a crude glycerine price
Glycerine has no single published price, but the arithmetic every buyer runs is public knowledge, and a seller who knows it reads an offer the way the other side does:
Compare per tonne of contained glycerol. At 80 % purity a tonne of crude is 800 kg of product; at 75 % it is 750. The difference between those two cargoes is not five percent of the price, it is the whole conversation.
Four numbers take specific discounts. MONG fouls the refiner's process, methanol adds handling and classification cost, salt narrows the buyer list, and water is freight. A low offer is usually an invoice for one of those four.
The floor is energy. In the worst market the molecule is still worth burning, and biogas operators price rough crudes as substrate on exactly that basis. Above the floor, refining value, feed eligibility under catalogue entry 13.8.1 and certification each add their own step.
Continuity earns the term premium. Monthly volume with a consistent analysis prices above one-off tanks, because the buyer is buying predictability as much as glycerol. Our how to sell glycerine guide works the same arithmetic from the seller's side, in full.
The physical constants a cargo plans around
Pure glycerol is a thick, heavy, water-loving liquid that sets well above zero, and four constants explain most of the freight bill and the storage discipline:
| Property | Value | What it decides |
|---|---|---|
| Melting point | 17.8 °C | Heated or insulated tanks from autumn to spring; solidified cargo is not spoiled, merely late and expensive |
| Density | 1.261 g/cm3 at 20 °C | A tank reaches its weight limit before it looks full: payload maths, not volume maths |
| Viscosity | 1.412 Pa·s at 20 °C | Over a thousand times water: slow loading, heated lines, patience at discharge |
| Flash point | 160 °C, closed cup | Well-stripped material is not a flammable cargo at ambient temperature; residual methanol changes that assessment |
| Boiling point | 290 °C | Distillation refining runs under vacuum for a reason |
| Water behaviour | Miscible in all proportions, hygroscopic | Picks up moisture in damp storage, and the buyer's certificate will find it |
The Annex IX angle worth knowing
Crude glycerine sits in Annex IX Part A at point (i) in Directive (EU) 2018/2001. Part A is the advanced category, which is a different and generally more favourable position than the Part B category that used cooking oil and category 1 and 2 animal fats occupy under a 1.7 % cap.
This matters because a good deal of crude glycerine is still sold as a low-value disposal problem by producers who treat it as waste from the biodiesel plant rather than as a listed advanced feedstock. Where the certification supports it, the biogas and advanced biofuel routes can pay materially better than the industrial default.
Annex IX has been amended since 2018, so confirm the current letter before writing it into a contract. The full lists are on our Annex IX reference page.
Where the world's glycerine comes from
Glycerine follows biodiesel and oleochemistry around the globe, and the origin decides as much of the commercial story as the purity does:
| Origin | The stream | What it means commercially |
|---|---|---|
| Brazil | 9.0 billion litres of biodiesel in 2024, about 73 percent of it from soybean oil, under a mandate that reached B15 in August 2025. | Soy-origin crude at world scale; see exporting glycerine from Brazil. |
| Indonesia and Malaysia | The largest palm biodiesel programme on earth -- Indonesia alone allocated 15.6 million kilolitres for 2025 under B40 -- plus the world's densest glycerine refining base. | Volume origin and refining competitor in one; see exporting glycerine from Asia. |
| China | Waste-based biodiesel for export, with a waste-origin glycerine co-product. | The origin file is the offer; the analysis still sets the band. |
| Europe | Rapeseed and waste-based biodiesel and oleochemical plants across the EU. | The nearest refining and biogas market -- Belgium and the Netherlands take rough crudes as digester substrate. |
| Argentina and North America | Soy biodiesel in Argentina, soy and canola programmes in the United States and Canada. | The same specification arithmetic, a different freight and paperwork file. |
We work the glycerine trade from all of these origins -- producers placing co-product streams, refiners and oleochemicals sourcing them, and biogas and feed buyers taking what the refiners do not want. Wherever a cargo sits, the five numbers are the same, and so is the door they open.
What a glycerine buyer will ask you
We act for biodiesel and oleochemical producers with continuous co-product to place, and for refiners, biogas operators and chemical buyers sourcing it. Glycerine production does not stop while a seller shops for a better number, so most of what we do here is term rather than spot: a reliable home for every batch, with the analysis, certification and tank logistics agreed once.
The grades, and the one number that decides the price
Glycerine is sold across a very wide quality range and the words people use for it are loose. What is not loose is the arithmetic.
| Crude glycerine | Straight from the biodiesel reactor. Typically 50 to 85 percent glycerol, with water, methanol, catalyst salts and MONG making up the rest. The 80 percent plus material trades readily; below that the conversation gets harder quickly. |
|---|---|
| Technical grade | Purified, commonly around 98 to 99 percent, for industrial use where pharmacopoeia compliance is not required. |
| Refined / USP / pharmacopoeia | Over 99.5 percent, for pharmaceutical, food and personal care use. A different market with different qualification requirements. |
| MONG | Matter Organic Non-Glycerol, and the number that most often decides whether a parcel moves. Calculated rather than measured directly: MONG = 100 minus glycerol, minus water, minus ash. ISO 2464 covers the calculation. It sweeps up free fatty acids, mono and diglycerides and everything else organic that is not glycerol. |
| Methanol | Residual from the transesterification. Well processed material keeps it below about 0.5 percent. It matters for classification and transport as well as for the buyer's process. |
| Ash | Catalyst salts, sodium or potassium depending which alkoxide the plant runs. See additives and blending on why that choice was made upstream. |
The practical read: a crude glycerine offer without glycerol content, water, ash, MONG and methanol on it is not an offer, it is an enquiry. Those five figures let a buyer calculate what they are actually paying for, and supplying them unprompted marks you out immediately. The full ladder -- technical and pharmacopoeia grades, sweet waters, soap lyes and residues -- is on our glycerine grades page.
Frequently asked questions
Glycerine, glycerin or glycerol -- same thing?
Yes, three names for one molecule. Glycerol is the chemical name (propane-1,2,3-triol, CAS 56-81-5), glycerine the usual British and trading spelling, glycerin the American one. Labels and safety data sheets mean the same substance either way; the specification, not the spelling, decides the price.
At what temperature does glycerine freeze?
Pure glycerol solidifies below 17.8 °C -- well above zero, which surprises people every autumn. Crude glycerine, with its water and salts, is somewhat more forgiving but still needs heated or insulated tanks and lines in the European winter. Solidified cargo is not spoiled, merely late and expensive to move.
Is glycerine flammable?
Not at ambient temperature: the flash point of pure glycerol is about 160 °C closed cup, and its boiling point is 290 °C. The exception is residual methanol in crude glycerine from transesterification -- methanol is a Class 3 flammable liquid, so a high methanol figure turns the cargo into a classification question before the truck is booked.
What salt level is too high for refiners?
Each refiner draws the line by plant design, high-salt crude narrowing the buyer list sharply, the number acting as a market filter. Salt is glycerine's class system.
Can crude glycerine be sold during plant upsets?
Off-quality glycerine sells at honest discounts to tolerant buyers, the market absorbing imperfection at a price as always. Upsets are invoices with a delay.
Is glycerine a commodity or speciality?
Crude is commodity, refined is speciality, the same molecule transforming across the purification ladder, value climbing with purity. Glycerine's ladder is its market.
What is glycerine's price floor?
Energy value in the worst markets, the molecule always worth burning, the floor rising with chemistry's demand from there. Glycerine falls to its calories and climbs to its chemistry.
Can glycerine be shipped in bulk containers?
ISO tanks are the crude standard, flexitanks where compatibility allows, drums for speciality lots, the viscosity and water discipline travelling with the cargo. Glycerine ships warm or ships slowly.
How should crude glycerine be stored?
In closed, ideally heated or insulated tanks, because glycerine thickens in cold and picks up water in damp, both of which the buyer's certificate will find. Warm, dry and closed is the storage trilogy.
What does a glycerine buyer ask about salt?
How much, because salt complicates refining economics and equipment, and high-salt crude narrows the buyer list. The salt number is a market filter wearing a lab coat.
Can crude glycerine move in ISO tanks in winter?
With heating or insulation on the route, yes, the standard winter provision for this cargo. Frozen glycerine is not spoiled, merely late and expensive.
How does a biodiesel plant sell its glycerine best?
On a consistent analysis with the methanol story clear, monthly volume committed, through buyers who value steadiness over spot edges. Glycerine rewards boring plants.
Is there a season in glycerine demand?
Less weather than industry cycles, with antifreeze and construction uses adding winter colour. The mandate calendar drives production, downstream industry drives consumption, and we watch both.
What is crude glycerine used for?
Refining into technical and pharma grades, animal feed at suitable purity, and industrial uses from antifreeze fluids to concrete additives. The biodiesel boom made crude glycerine abundant, which is why the market pays for purity and consistency rather than for glycerol that still carries methanol, salt and soaps.
Why is glycerine called crude or technical grade?
Crude is what leaves the biodiesel plant, typically 80 percent glycerol with methanol, salt, water and MONG, the matter organic non glycerol. Technical grade is refined to high purity for industrial use. The grade names are really price bands, and the MONG and methanol numbers decide which band a cargo falls into.
How is crude glycerine transported?
In insulated or heated ISO tanks and IBCs, because glycerine thickens in cold weather, with material choice following the salt and methanol content. The same cargo that pumps easily in July needs heated equipment in January, which is why winter placement is a logistics conversation before it is a price one.
Can crude glycerine be refined at source?
Yes, and for steady volumes it often pays: distillation lifts the cargo from crude value into technical grade. Whether the capital and energy cost clear depends on volume and consistency, a calculation we run with producers before anyone orders columns.
What is MONG in glycerine and why does everyone ask about it?
MONG is Matter Organic Non-Glycerol: everything organic in the parcel that is not glycerol, such as free fatty acids and mono and diglycerides. It is calculated rather than measured, as 100 minus glycerol, minus water, minus ash, with ISO 2464 covering the calculation. Buyers ask because it tells them what they are paying to remove. A high MONG figure moves a parcel from a refining feed to a biogas or disposal conversation.
What should be on a crude glycerine offer?
Five numbers, and without them it is an enquiry rather than an offer: glycerol content, water, ash, MONG and residual methanol. Add origin, monthly volume and certification status and a buyer can price it on the spot. Typical crude from biodiesel runs 50 to 85 percent glycerol, with the 80 percent plus material moving much more easily than material below that.
Is crude glycerine an Annex IX feedstock?
Yes. Crude glycerine is listed in Annex IX Part A at point (i) of Directive (EU) 2018/2001, which places it in the advanced feedstock category rather than the capped Part B category. Annex IX has been amended since, so confirm the current letter against the consolidated text before contracting.
What is MONG in a glycerine specification?
Matter organic non-glycerol: the organic impurity content beyond glycerol and water. It is the best single indicator of how difficult and expensive the material will be to refine, which is why refiners price against it directly rather than against purity alone.
What purity is crude glycerine?
Typically around 80 % glycerol, though it varies with the plant and the feedstock. Refined and technical grades run 99 % and above. The gap between the two is refining capacity, and access to a refiner is often worth more to a producer than a point of purity.
Why does methanol content matter?
It is residual from transesterification and it is a safety, transport and classification issue as much as a quality one. Buyers and terminals both ask about it early, and a high figure narrows the list of parties who can legally handle the cargo.
Can glycerine go to biogas?
Yes, and it is a well-established outlet. Crude glycerine is a readily digestible, energy-dense co-substrate for anaerobic digestion. Whether it is worth more there than in a refining or chemical outlet depends on purity, salt content, certification and location.
Do you handle refined and pharmaceutical grade?
Yes, though the buyer list narrows sharply as the specification tightens, and USP and pharmaceutical grades carry documentation requirements well beyond a normal certificate of analysis. Tell us the grade and the intended use and we will say plainly whether we are the right broker for it.
Market news
Recent headlines from across the feedstock and renewable fuel sector. Nothing specific to this market has come through the wires lately, so this is the wider view. The links go to the publisher; we do not host or edit their reporting, and a headline here is not our endorsement of it. Scroll for more.
- The Digest’s 2026 Multi-Slide Guide to Pipeline Access for Biofuels
- Scientists urged to crack green hydrogen cost barrier
- Neste and United Airlines extend SAF agreement
- WELTEC BIOPOWER begins construction of 60GW Spanish biomethane plant
- U.S. ethanol exports set new records
- FedEx expanding SAF procurement across five US airports in 2027
- Pertamina seeks ethanol import excise exemption
- Senate advances bill to allow year-round E15
- The Digest’s 2026 Multi-Slide Guide to Regional SAF Distribution
- Research and innovation projects supporting the Circular Economy Act Focus area : extended producer responsibility
- Ecodesign for Sustainable Products Regulation: Stakeholder consultation on the methods for defining classes of performance and labels
- Research and innovation projects supporting the Circular Economy Act, Focus area : circular public procurement
- Ecodesign for Sustainable Products Regulation: Stakeholder consultation on the method for identifying and tracking substances of concern in products
- Birla Carbon to present ‘next-generation carbon solutions’ at Global Polymer Summit 2026
- ‘World’s first hydrogen-fuelled engine for large commercial vessels’ completes land-based testing
- Moeve breaks ground on renewable hydrogen project
- Yokogawa wins order from KHI for hydrogen-fuelled vessels
- Azane and Yara ink ammonia supply agreement
18 headlines, updated automatically. Last refreshed .
Sources and further reading
Primary sources for the rules and figures on this page, so you can check them yourself. Legislation is amended: always read the consolidated text on the date that matters to you.
- Document checklist: exactly which papers a European buyer asks for, per product
- SPECIMEN safety data sheet: Crude glycerine (worked example, all 16 sections)
- Glycerine grade specifications, crude through USP
- Directive (EU) 2018/2001 (RED II), consolidated text on EUR-Lex
- Directive (EU) 2023/2413 (RED III) on EUR-Lex
- ISCC System, the certification scheme itself
Who to ask about Crude & refined glycerine
Just ask. Glycerine to place? Send the purity, the MONG, the ash and the methanol figure and we will tell you which market you are in. You get Bart van den Brug on the other end, same working day, in English or Dutch, and across the team also in French, Portuguese, Polish, Czech and Russian.
On how we work: on the feedstocks and fuels on this site we are a broker. We never take title, we do not trade our own book, and we are paid a commission on business that concludes. Additives are the one exception: those we also buy and sell for our own account, and we say in which capacity we are acting before you commit to anything. Either way you will hear it from us when the answer is no, or when your parcel is not ready for the conversation you want to have. A market read or a second opinion on a specification costs nothing and commits you to nothing.
Happy to look at whatever you have, even if it is half an analysis and a question.
+31 6 115 83 448
bart@sustainablecommodities.eu
Sustainable Commodities 3 B.V., Lemmer, the Netherlands
Ask about Crude & refined glycerine
Specification, volume, location and certification are enough to start.
Or e-mail us directly: bart@sustainablecommodities.eu
Last reviewed 21 September 2026. Regulatory references are given for orientation and are not legal advice: verify against the current Official Journal text before contracting.